More black than white celebrities are active Twitter users; Shaquille O'Neal, Oprah, 50 Cent, and P Diddy are all among the most followed accounts on Twitter. That's great publicity for Twitter, and could be helping Twitter become more mainstream among black people.
The median age for black Americans (according to the 2000 census) is 30 years old, a full seven years younger than for white Americans. Black people therefore make up a relatively higher percentage of the population within the most relevant age groups -- Twitter is most popular amongst 25-34 year-olds.
Those are the best explanations we can come up with. Any thoughts?